A natural restorative (5)
I believe the answer is:
sleep
'a natural restorative' is the definition.
Although both the answer and definition are singular nouns, I don't see how one could define the other.
This is all the clue.
Can you help me to learn more?
(Other definitions for sleep that I've seen before include "Produced (egg)" , "Natural state of unconscious rest" , "Snooze" , "Slumber" , "crash" .)