Chuck out defective item without opening (5)
I believe the answer is:
eject
'chuck out' is the definition.
(synonyms)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for eject that I've seen before include "DVD player button" , "exile" , "Throw out (e.g. of plane)" , "Turf out" , "Spit out" .)