Like a rough diamond when sober? (5)
I believe the answer is:
uncut
'like' is the definition.
Both the definition and answer are adjectives. Perhaps you can see a link between them that I can't see?
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for uncut that I've seen before include "as originally intended" , "Not abridged" , "Without abridgement" , "diamonds, originally" , "(Of a diamond) rough" .)