Old chap — one from SW Asian country (5)
I believe the answer is:
omani
'sw asian country' is the definition.
I can't tell whether this defines the answer.
'old chap one' is the wordplay.
'old' becomes 'o' (abbreviation).
'chap' becomes 'man' (chap can mean a man).
'one' becomes 'i' (Roman numeral).
'o'+'man'+'i'='OMANI'
'from' acts as a link.
Can you help me to learn more?
(Other definitions for omani that I've seen before include "one from the Middle East" , "Middle East national" , "Gulf native" , "M East person" , "One from Muscat" .)