Parking in the wrong one, to start with (4)
I believe the answer is:
open
'start with' is the definition.
'open' can be an answer for 'start' (opening is a kind of starting). I'm not sure about the 'with' bit.
'parking in the wrong one' is the wordplay.
'parking' becomes 'p' (abbreviation on road signs).
'in' indicates putting letters inside.
'the wrong' indicates an anagram.
'one' is an anagram of 'oen'.
'p' going inside 'oen' is 'OPEN'.
'to' acts as a link.
Can you help me to learn more?
(Other definitions for open that I've seen before include "yawning" , "Undo; exposed to attack" , "Uncovered" , "such a verdict?" , "Frank - ready for business" .)