Pay out some subs twice (6)
I believe the answer is:
double
'twice' is the definition.
(synonyms)
'pay out some subs' is the wordplay.
'pay' becomes 'dole' (I can't justify this - if you can you should believe this answer much more).
'out' indicates putting letters inside.
'some' means to look at the middle letters.
The middle letters of 'subs' are 'ub'.
'dole' enclosing 'ub' is 'DOUBLE'.
Can you help me to learn more?
(Other definitions for double that I've seen before include "Make twice as many" , "Increase twofold" , "Twice the amount" , "Person who says one thing and does another" , "- - -u, (w)" .)