Stack bordering large field (5)
I believe the answer is:
realm
'field' is the definition.
(synonyms)
'stack bordering large' is the wordplay.
'stack' becomes 'ream' (I am not sure about this - if you are sure you should believe this answer much more).
'bordering' is an insertion indicator.
'large' becomes 'L' (eg in clothes sizes).
'ream' enclosing 'l' is 'REALM'.
Can you help me to learn more?
(Other definitions for realm that I've seen before include "World" , "Kingdom, or field of activity" , "King's domain" , "department" , "Province" .)