The cleaner was not him! (6)
I believe the answer is:
washer
'the cleaner' is the definition.
(I've seen this before)
'was not him' is the wordplay.
'not him' becomes 'her' (I've seen this in another clue).
'was'+'her'='WASHER'
(Other definitions for washer that I've seen before include "Cleaner" , "Joint-sealing ring" , "Seal preventing leakage" , "Tap seal" , "Plumber's rubber ring" .)