Very desirable bachelor perfectly erect (5)
I believe the answer is:
plumb
'erect' is the definition.
(thesaurus)
'very desirable bachelor perfectly' is the wordplay.
'very desirable' becomes 'plum' (plum can mean excellent).
'bachelor perfectly' becomes 'b' (abbreviation e.g. BA=Bachelor of Arts. I am not sure about the 'perfectly' bit.).
'plum'+'b'='PLUMB'
Can you help me to learn more?
(Other definitions for plumb that I've seen before include "Precisely" , "Exactly - . . . . . in the middle" , "Check depth of water below" , "Get to the bottom of the matter or depths" , "Utterly" .)