Wedding day ultimately ruined after bride's heart rejected somewhere in Wales (7)
I believe the answer is:
gwynedd
'wales' is the definition.
Both the answer and definition are singular nouns.
Perhaps you can see an association between them that I don't see?
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for gwynedd that I've seen before include "County of north-west Wales" , "Area of north-west Wales" , "Bangor's county" , "Welsh county" .)