A barney colour (4)
I believe the answer is:
blue
'colour' is the definition.
(blueing is a kind of colouring)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for blue that I've seen before include "Colour of depression" , "Turquoise, say" , "Spend all at once - colour" , "University sportsman - a shade - depressed" , "Down in the mouth" .)