A black eye, it seems, shows brilliance! (6)
I believe the answer is:
shiner
'a black eye' is the definition.
(I know that black eye can be written as shiner)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for shiner that I've seen before include "A black eye, colloquially" , "injury to face?" , "Black eye - small glittering fish" , "What one might get from boxer" , "Informally, a black eye" .)