A Bond villain unmasked as Italian banker (4)
I believe the answer is:
arno
'banker' is the definition.
(I've seen this before)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for arno that I've seen before include "River of 4 down?" , "River in central Italy" , "River of 11 across" , "Pisa's river" , "River flowing through Florence and Pisa" .)