A box of vital personal possessions (5)
I believe the answer is:
chest
'a box' is the definition.
(chest is a kind of box)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for chest that I've seen before include "Trunk or crate" , "Strong box; thorax" , "Upper trunk" , "Part of body; storage box" , "Large box used for storage" .)