A brown one is no rainbow! (5)
I believe the answer is:
trout
'rainbow' is the definition.
(I've seen this before)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for trout that I've seen before include "Tasty fish, brown or rainbow" , "one of a noted quintet" , "Fish - old harridan" , "Unattractive old woman" , "one often tickled?" .)