A capital Italian perfume (5)
I believe the answer is:
aroma
'italian perfume' is the definition.
'aroma' can be an answer for 'perfume' (synonyms). I'm not certain of the 'italian' bit.
'a capital' is the wordplay.
'capital' becomes 'roma' (Roma is an example).
'a'+'roma'='AROMA'
Can you help me to learn more?
(Other definitions for aroma that I've seen before include "Strong smell" , "Pervasive quality" , "Scent - fragrance" , "A pleasant smell as of food" , "Spicy fragrance" .)