A capital orchestra, too! (4)
I believe the answer is:
also
'too' is the definition.
(synonyms)
'a capital orchestra' is the wordplay.
'capital orchestra' becomes 'lso' (London Symphony Orchestra. I am not sure about the 'capital' bit.).
'a'+'lso'='ALSO'
Can you help me to learn more?
(Other definitions for also that I've seen before include "into the bargain" , "Item" , "Furthermore" , "revolutionary a part for Yugoslavia" , "Old" .)