A charge on collection (5)
I believe the answer is:
onset
'a charge' is the definition.
(thesaurus)
'on collection' is the wordplay.
'collection' becomes 'set' (set is a kind of collection).
'on'+'set'='ONSET'
(Other definitions for onset that I've seen before include "Start - notes (anag)" , "Beginning or early stages" , "Appearance of" , "Outbreak" , "Beginning; military attack" .)