A chief is leading (5)
I believe the answer is:
ahead
'is leading' is the definition.
(to lead is to go ahead)
'a chief' is the wordplay.
'chief' becomes 'head' (synonyms).
'a'+'head'='AHEAD'
(Other definitions for ahead that I've seen before include "In the leading position" , "advanced" , "Forward - in front" , "Winning" , "at pole" .)