A couple from Austria go peculiar (7)
I believe the answer is:
strange
'peculiar' is the definition.
(synonyms)
'a couple from austria go' is the wordplay.
'a couple from austria' becomes 'st' (I can't justify this - if you can you should believe this answer much more).
'go' becomes 'range' (ranging is a kind of going).
'st'+'range'='STRANGE'
Can you help me to learn more?
(Other definitions for strange that I've seen before include "Queer" , "Odd - rum" , "Unknown or peculiar" , "Different" , "Weird, eerie" .)