A darn bookend packed crookedly (5)
I believe the answer is:
askew
'crookedly' is the definition.
(I've seen this before)
'a darn bookend packed' is the wordplay.
'darn' becomes 'sew' (I've seen this in another clue).
'bookend' becomes 'k' (I can't justify this - if you can you should give a lot more credence to this answer).
'packed' is an insertion indicator (some letters are packed into others).
'sew' enclosing 'k' is 'skew'.
'a'+'skew'='ASKEW'
Can you help me to learn more?
(Other definitions for askew that I've seen before include "Not straight or level, crooked" , "Towards one side, awry" , "Wakes (anag)" , "Lopsided" , "Off-centre" .)