A face isn't made to beguile (9)
I believe the answer is:
fascinate
'beguile' is the definition.
('fascinate' can be a synonym of 'beguile')
'a face isn't made' is the wordplay.
'made' is an anagram indicator.
'a'+'face'+'isnt'='afaceisnt'
'afaceisnt' anagrammed gives 'FASCINATE'.
'to' is the link.
(Other definitions for fascinate that I've seen before include "Captivate" , "Charm" , "Enchant - beguile" , "Irresistibly interest" , "Intrigue" .)