A flower instead of a half of bitter (5)
I believe the answer is:
aster
'a flower' is the definition.
(type of flower)
'instead of a half of bitter' is the wordplay.
'instead of' becomes 'as' (I am not sure about this - if you are sure you should believe this answer much more).
'a half of' indicates taking half.
'bitter' halved is 'ter'.
'as'+'ter'='ASTER'
Can you help me to learn more?
(Other definitions for aster that I've seen before include "Plant like a Michaelmas daisy" , "bloomer" , "Flowering plant; tares (anag.)" , "Daisy-like garden flower" , "Flower of the daisy family - rates (anag)" .)