A gem of a green (7)
I believe the answer is:
emerald
I believe this clue is a double definition.
'a gem' is the first definition.
(type of gem stone)
'a green' is the second definition.
(emerald is a shade of green)
'of' acts as a link.
(Other definitions for emerald that I've seen before include "Precious green stone" , "Green gemstone" , "Gem associated with Ireland" , "La couleur" , "and 1 Across: Ireland" .)