A hugely experienced topiarist? That's Serpent! (10)
I believe the answer is:
bushmaster
This clue could be a double definition.
'a hugely experienced topiarist?' is the first definition.
The definition suggests a singular noun which matches the answer.
'serpent' is the second definition.
Both the answer and definition are singular nouns.
Maybe there's a link between them I don't understand?
'that's' is the link.
Can you help me to learn more?
(Another definition for bushmaster that I've seen is " Pit viper; sham brutes (anag.)".)