A labyrinth's floor (5)
I believe the answer is:
amaze
'floor' is the definition.
(I've seen this before)
'a labyrinth's' is the wordplay.
'labyrinth' becomes 'maze' ('maze' can be a synonym of 'labyrinth').
'a'+'maze'='AMAZE'
(Other definitions for amaze that I've seen before include "wow!" , "Greatly surprise, fill with wonder" , "Bewilder" , "Stagger" , "Greatly surprise in a labyrinth" .)