A London orchestra as well (4)
I believe the answer is:
also
'as well' is the definition.
(synonyms)
'a london orchestra' is the wordplay.
'london orchestra' becomes 'LSO' (london symphony orchestra).
'a'+'lso'='ALSO'
(Other definitions for also that I've seen before include "into the bargain" , "Likewise" , "in accompaniment" , "'Besides, moreover (4)'" , "on top" .)