A loose wide-sleeved liturgical vestment worn over the cassock by clergymen, choristers and acolytes (8)
I believe the answer is:
surplice
(Other definitions for surplice that I've seen before include "White vestment worn over a cassock" , "I scruple to wear priestly garment" , "Clerical or choral garment" , "White gown worn over a cassock" , "gear" .)