A loveless lover, but capital (4)
I believe the answer is:
rome
'capital' is the definition.
(capital of Italy)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for rome that I've seen before include "Italian city" , "All roads lead to it" , "Basis for cheese" , "Colosseum city" , "When there, do as the native do" .)