A meal with a companion can be instructive (5)
I believe the answer is:
teach
'be instructive' is the definition.
I can't tell whether this definition defines the answer.
'a meal with a companion' is the wordplay.
'a meal' becomes 'tea' (tea is a type of meal).
'with' is a charade indicator (letters next to each other).
'a companion' becomes 'ch' (Companion of Honour).
'tea'+'ch'='TEACH'
'can' acts as a link.
Can you help me to learn more?
(Other definitions for teach that I've seen before include "Act as director" , "Work in school" , "Convey knowledge to students" , "Coach" , "Cheat (anag)" .)