A means of access for jeweller’s stone (5)
I believe the answer is:
agate
'jeweller's stone' is the definition.
'a means of access' is the wordplay.
'means of access' becomes 'gate'.
'a'+'gate'='AGATE'
'for' is the link.
(Other definitions for agate that I've seen before include "Semi-precious quartz" , "Hard stone with concentric bands of colour" , "Type of quartz" , "marble" , "rock with bands" .)