Crossword Genius

A most unusual arrow poison (6)

Ross

I believe the answer is:

curare

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'arrow poison' is the definition.
(I've seen this before)

'a most unusual' is the wordplay.
'a most' becomes 'cu' (I can't justify this - if you can you should give a lot more credence to this answer).
'unusual' becomes 'rare' (rare can mean unusual or odd).
'cu'+'rare'='CURARE'

Can you help me to learn more?

(Other definitions for curare that I've seen before include "Poison used on darts" , "Paralysing plant poison" , "Poison put on arrows" , "Arrow poison" , "Poison applied to darts" .)

I've seen this clue in the Evening Standard.
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