A nymph puts a spell on one (5)
I believe the answer is:
houri
'a nymph' is the definition.
(I know that nymph can be written as houri)
'a spell on one' is the wordplay.
'a spell on' becomes 'hour' (I can't explain this - if you can you should give a lot more credence to this answer).
'one' becomes 'I' (Roman numeral).
'hour'+'i'='HOURI'
'puts' is the link.
Can you help me to learn more?
(Other definitions for houri that I've seen before include "Young beautiful woman of the Moslem Paradise" , "Voluptuous female" , "Beautiful female" , "Alluring woman or nymph in Muslim paradise" , "Alluring female" .)