A peculiar plant (4)
I believe the answer is:
arum
'plant' is the definition.
(arum is a kind of plant)
'a peculiar' is the wordplay.
'peculiar' becomes 'rum' (synonyms).
'a'+'rum'='ARUM'
(Other definitions for arum that I've seen before include "Cuckoo pint genus" , "genus of plants" , "Plant like cuckoo pint" , "A spirit for a lily" , "Eg, cuckoo pint" .)