A poisonous sort of “ology” (5)
I believe the answer is:
toxic
'a poisonous' is the definition.
(I've seen this before)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for toxic that I've seen before include "word describing bad things" , "Deadly - venomous" , "Poisonous, noxious" , "Harmful - cox it (anag)" .)