A punchy pair? (5)
I believe the answer is:
socks
'pair?' is the definition.
(I have seen 'pair of garments' mean 'socks' so perhaps 'pair' could also mean 'socks')
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for socks that I've seen before include "Hits; some clothing" , "Hard blows" , "Footwear - strikes" , "Half-hose" , "Hits forcefully (colloq.)" .)