A quantity of pickled peppers picked to nibble (4)
I believe the answer is:
peck
This clue is a double definition.
'a quantity of pickled peppers picked' is the first definition.
('Peter Piper picked a peck of pickled peppers')
'to nibble' is the second definition.
(I've seen this before)
(Other definitions for peck that I've seen before include "Large number" , "Nibble" , "Strike with beak" , "Gregory" , "Light kiss; measure" .)