A revolutionary form of suffering (4)
I believe the answer is:
ache
'form of suffering' is the definition.
(type of pain)
'a revolutionary' is the wordplay.
'revolutionary' becomes 'che' (Che Guevara the Marxist revolutionary).
'a'+'che'='ACHE'
(Other definitions for ache that I've seen before include "Long ? pain" , "Nagging pain" , "Persistent dull pain" , "Shakespearean character" , "Play up" .)