A rhyme is troublesome (8)
I believe the answer is:
perverse
'troublesome' is the definition.
Both the definition and answer are adjectives. Maybe there's a link between them I don't understand?
'a rhyme' is the wordplay.
'a' becomes 'per' (eg 'one a day' means 'one per day').
'rhyme' becomes 'verse' (synonyms).
'per'+'verse'='PERVERSE'
'is' acts as a link.
Can you help me to learn more?
(Other definitions for perverse that I've seen before include "Deviant" , "Disposed to oppose and contradict" , "Wrongly determined" , "Obstinately wrong-headed" , "It's wrong" .)