A rigorous preparation for toning the skin (10)
I believe the answer is:
astringent
'preparation for toning the skin' is the definition.
I can't judge whether this defines the answer.
'a rigorous' is the wordplay.
'rigorous' becomes 'stringent' ('stringent' can be a synonym of 'rigorous').
'a'+'stringent'='ASTRINGENT'
Can you help me to learn more?
(Other definitions for astringent that I've seen before include "Caustic" , "for checking bleeding" , "biting" , "Scathing" , "Sharp or severe in manner" .)