A row among the frontiersmen (4)
I believe the answer is:
tier
'a row' is the definition.
(a tier is a row of things)
'among the frontiersmen' is the wordplay.
'among' indicates a hidden word.
'TIER' is hidden in the letters of 'frontiersmen'.
(Other definitions for tier that I've seen before include "he hasn't won?" , "Rite (anag.)" , "Row (of seats)" , "Row in theatre" , "'Level, grade (4)'" .)