A ruminant's heading off south of capital of Kenya, African city (7)
I believe the answer is:
kampala
'city' is the definition.
(Kampala is an example)
'a ruminant's heading off south of capital of kenya african' is the wordplay.
'a ruminant' becomes 'impala' (impala is a kind of ruminant).
'heading off' means to remove the first letter.
'south of' is a charade indicator (letters next to each other).
'capital of kenya african' becomes 'ka' (I am not sure about this - if you are sure you should believe this answer much more).
'impala' with its first letter taken away is 'mpala'.
'mpala' after 'ka' is 'KAMPALA'.
Can you help me to learn more?
(Other definitions for kampala that I've seen before include "Capital of Uganda" , "Uganda's capital" , "Ugandan city" , "Ugandan capital" , "in East Africa" .)