A shiner, it seems, will make you scowl (6)
I believe the answer is:
glower
'scowl' is the definition.
(I've seen this before)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for glower that I've seen before include "Angry stare" , "Look hard and angrily" , "Angry and sullen look" , "shiner?" , "Look black" .)