A shipmaster, when not at sea, ordered seafood (6)
I believe the answer is:
shrimp
'seafood' is the definition.
(shrimp is a kind of seafood)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for shrimp that I've seen before include "Runt" , "very small one" , "Raising of a siege" , "School member" , "Diminutive person" .)