A snake on the road and on to a vessel (6)
I believe the answer is:
aboard
'on to a vessel' is the definition.
I can't tell whether this defines the answer.
'a snake on the road' is the wordplay.
'snake' becomes 'boa' (boa constrictor, type of snake).
'on' is a charade indicator (letters next to each other).
'the road' becomes 'rd' (abbreviation).
'a'+'boa'+'rd'='ABOARD'
'and' is the link.
Can you help me to learn more?
(Other definitions for aboard that I've seen before include "On vessel or vehicle" , "On (eg, a ship)" , "On an aircraft" , "Joined for mutual benefit" , "... [CRUISE SHIP] here, perhaps" .)