A solitary pupil - one (4)
I believe the answer is:
lone
'a solitary' is the definition.
(thesaurus)
'pupil one' is the wordplay.
'pupil' becomes 'l' (**).
'l'+'one'='LONE'
(Other definitions for lone that I've seen before include "Single and isolated" , "He likes to operate by himself" , "Solitary, without companions" , "The ... Ranger, fictional masked cowboy" , "Companionless" .)