A tin's possible discolouration (5)
I believe the answer is:
stain
'discolouration' is the definition.
(synonyms)
'a tin's possible' is the wordplay.
'a tin's' anagrams to 'STAIN'.
However, I am not sure how the anagram is indicated.
Can you help me to learn more?
(Other definitions for stain that I've seen before include "Blotch on satin" , "Mark with colour, dirt" , "Tarnish" , "Discolour - blemish" , "Discoloured patch" .)