A young lady at fault (5)
I believe the answer is:
amiss
'at fault' is the definition.
(thesaurus)
'a young lady' is the wordplay.
'young lady' becomes 'miss' ('miss' can be a synonym of 'young lady'**).
'a'+'miss'='AMISS'
(Other definitions for amiss that I've seen before include "Taking wrong turn" , "Haywire" , "inappropriately" , "astray" , "Fallacious" .)