Acts as executioner. Some teachers want to! (7)
I believe the answer is:
beheads
'want to' is the definition.
I can't tell whether this defines the answer.
'acts as executioner some teachers' is the wordplay.
'acts as' becomes 'b' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'some' says to take the initial letters.
'teachers' becomes 'heads' (head or headteacher is a type of teacher).
The initial letter of 'executioner' is 'e'.
'b'+'e'+'heads'='BEHEADS'
Can you help me to learn more?
(Another definition for beheads that I've seen is " Decapitates".)