Add a little whisky, perhaps (3)
I believe the answer is:
tot
'add' is the definition.
(synonyms)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for tot that I've seen before include "Add up like infant" , "A wee dram" , "Sum for the little one" , "Child's" , "nipper" .)